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Congress admitted Maine to the Union as a separate free state in 1820 to balance the admission of Missouri, a slave state. The balance of free and slaveholding states established by the Missouri Compromise did not last however. Another compromise on the extension of slavery in 1850 eventually failed, and the nation headed toward civil war.
Sec. 2. Be it enacted . . . , That the inhabitants of that portion of the Missouri Territory . . . are hereby, authorized to form for themselves a Constitution and State Government, . . . and the said State, when formed, shall be admitted into the Union, upon an equal footing with the original states, in all respects whatsoever.
Records of the U.S. Senate, National Archives and Records Administration